Preheat an oven to 350°F.
Lightly oil a 12-cup bundt pan.
In a bowl, stir together the
flour, granulated sugar, cocoa, baking soda, baking powder, and salt. Add
the buttermilk, brown sugar, eggs, oil, and vanilla and beat for 2 minutes
until well incorporated. Stir in the hot coffee until completely
incorporated. (The batter will be thin.) Pour into the prepared bundt pan.
Bake for 35 to 40 minutes, or
until a knife comes out clean. Let cool in the pan on a rack for 10
minutes, then turn out onto the rack and let cool completely.
To make the frosting, in a
bowl, beat together the confectioners' sugar, vanilla, and enough
buttermilk or milk to make a thick but pourable frosting. Drizzle the
frosting evenly over the top of the cake.